If i understand correctly, you want to run a "reverse" reverse proxy configuration (i.e. a failsafe proxy configuration). In the HTTP case, when your internal clients connect to 192.168.0.10:80, they will be redirected to some random provider server on port 80. But what happens there? Most probably, your internal clients will see randomly one of the three providers homepages, which is not what you want.
It should be possible to configure pound as a ordinary proxy in your clients and let pound connect to one the proxies of the three providers (most likely on a port different to 80). This could work, but we use pound only in the true reverse case.
not sure, if this helps.
-gustaf